论文标题
化学反应中手性映异构体形成的真空诱导的对称性断裂
Vacuum-Induced Symmetry Breaking of Chiral Enantiomer Formation in Chemical Reactions
论文作者
论文摘要
内部破裂的材料可以通过真空电磁波动将对称性闯入其附近。在这里，我们表明，靠近平等对称性的材料的真空量子波动可以诱导手性分子的手性依赖性光谱移位，从而产生了化学反应过程，该过程有利于产生一种刺耳性而不是另一种。我们通过实验可实现的参数来计算具体的示例，并评估手性生产率，显示出使用对称性真空量子波动选择手性的希望。
A material with symmetry breaking inside can transmit the symmetry breaking to its vicinity by vacuum electromagnetic fluctuations. Here, we show that vacuum quantum fluctuations proximate to a parity-symmetry-broken material can induce a chirality-dependent spectral shift of chiral molecules, resulting in a chemical reaction process that favors producing one chirality over the other. We calculate concrete examples and evaluate the chirality production rate with experimentally realizable parameters, showing the promise of selecting chirality with symmetry-broken vacuum quantum fluctuations.
