论文标题

可视化大规模WSE $ _2 $/Bifeo $ _3 $异质结构中的巨型铁电控效效果

Visualizing giant ferroelectric gating effects in large-scale WSe$_2$/BiFeO$_3$ heterostructures

论文作者

Salazar, Raphaël, Varotto, Sara, Vergnaud, Céline, Garcia, Vincent, Fusil, Stéphane, Chaste, Julien, Maroutian, Thomas, Marty, Alain, Bonell, Frédéric, Pierucci, Debora, Ouerghi, Abdelkarim, Bertran, François, Fèvre, Patrick Le, Jamet, Matthieu, Bibes, Manuel, Rault, Julien

论文摘要

基于量子材料(复杂的氧化物,拓扑绝缘子,过渡金属二盐元素等)的多层已经实现了可以彻底改变微电子和光电子的设备的设计。但是,结合来自不同家庭的量子材料的异质结构仍然很少,而它们将极大地扩大可能的应用范围。在这里,我们证明了来自两个高度功能的家族的化合物的大规模整合:钙钛矿氧化物和过渡金属二核苷(TMDS)。我们将bifeo $ _3 $(一种室温多种氧化物)和WSE $ _2 $,一种半导体的二维材料,具有光伏和光子学的潜力。 WSE $ _2 $是由分子束外延生长的,并以厘米级转移到Bifeo $ _3 $胶片上。使用角度分辨的光发射光谱法,我们可视化1至3个WSE $ _2 $的1至3个单层的电子结构,并证明了巨大的能量转移,其巨大的能量移动是由基础Bifeo Bifeo $ _3 $中的铁电偏振方向引起的0.75 eV。这种强劲的转变为通过接近性效应有效地操纵TMDS性能开辟了新的观点。

Multilayers based on quantum materials (complex oxides, topological insulators, transition-metal dichalcogenides, etc) have enabled the design of devices that could revolutionize microelectronics and optoelectronics. However, heterostructures incorporating quantum materials from different families remain scarce, while they would immensely broaden the range of possible applications. Here we demonstrate the large-scale integration of compounds from two highly-multifunctional families: perovskite oxides and transition-metal dichalcogenides (TMDs). We couple BiFeO$_3$, a room-temperature multiferroic oxide, and WSe$_2$, a semiconducting two-dimensional material with potential for photovoltaics and photonics. WSe$_2$ is grown by molecular beam epitaxy and transferred on a centimeter-scale onto BiFeO$_3$ films. Using angle-resolved photoemission spectroscopy, we visualize the electronic structure of 1 to 3 monolayers of WSe$_2$ and evidence a giant energy shift as large as 0.75 eV induced by the ferroelectric polarization direction in the underlying BiFeO$_3$. Such a strong shift opens new perspectives in the efficient manipulation of TMDs properties by proximity effects.

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