论文标题

在自组装的FERH纳米磁体中保存元磁主义

Preserving Metamagnetism in Self-Assembled FeRh Nanomagnets

论文作者

Motyčková, Lucie, Arregi, Jon Ander, Staňo, Michal, Průša, Stanislav, Částková, Klára, Uhlíř, Vojtěch

论文摘要

我们提出了使用溅射沉积处理的元磁纳米岛阵列的自组装途径。控制生长参数和外观允许调整Ferh纳米群岛的大小和形状。虽然在氧化物底物上通过热力学成核形成在氧化物底物形成的纳米群中,抗铁磁剂和铁磁序之间的相变很大程度上被抑制,但我们发现元磁主义在很大程度上保存在通过固态脱水形成的纳米磁性阵列中。这种行为在很大程度上取决于纳米群岛的产生晶体,这是每个组装途径的特征。比较纳米群岛每个磁相计算的表面能,表明可以通过各个方面的特定几何结构来抑制或允许元磁性。此外,我们发现空间限制会导致非常明显的超冷和纳米群岛的相位分离。最后,将支持的纳米磁体从底物上化学蚀刻,以检查自动纳米颗粒的相变特性。我们证明,固态易碎是一种可行且可扩展的方法,可获取具有保留的元磁性的支持和独立的FERH纳米磁体。

We present self-assembly routes of metamagnetic FeRh nanoisland arrays using sputter deposition processing. Controlling the growth parameters and epitaxy allows tuning the size and shape of the FeRh nanoislands. While the phase transition between antiferromagnetic and ferromagnetic order is largely suppressed in nanoislands formed on oxide substrates via thermodynamic nucleation, we find that metamagnetism is largely preserved in nanomagnet arrays formed through solid-state dewetting. This behavior is strongly dependent on the resulting crystal faceting of the nanoislands, which is characteristic of each assembly route. Comparing the calculated surface energies for each magnetic phase of the nanoislands reveals that metamagnetism can be suppressed or allowed by specific geometrical configurations of the facets. Furthermore, we find that the spatial confinement leads to very pronounced supercooling and the absence of phase separation in the nanoislands. Finally, the supported nanomagnets are chemically etched away from the substrates to inspect the phase transition properties of self-standing nanoparticles. We demonstrate that solid-state dewetting is a feasible and scalable way to obtain supported and free-standing FeRh nanomagnets with preserved metamagnetism.

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