论文标题

在Almahata Sitta陨石中检测宇宙富勒烯:它们是星际遗产吗?

Detection of Cosmic Fullerenes in the Almahata Sitta Meteorite: Are They an Interstellar Heritage?

论文作者

Sabbah, Hassan, Carlos, Mickaël, Jenniskens, Peter, Shaddad, Muawia, Duprat, Jean, Goodrich, Cyrena, Joblin, Christine

论文摘要

Buckminsterfullerene(C60)是迄今为止在星际和情节环境中观察到的最大分子。该分子形成的机理被积极争论。尽管针对原始碳质软管进行了针对性的搜索,但迄今为止,尚未在陨石中发现C60的明确检测。在这里,我们报告了在Almahata Sitta(AHS)Polymict ureilite陨石中对富勒烯的第一个公司发现,从C30到C100至少C100。使用高敏感的激光脱附激光电离质谱法实现了这种检测。在七个AHS尿路碎片中,富勒烯已被明确检测到。分子家族分析表明,与在同一样品中检测到的多环芳烃相比,富勒烯来自不同的储层。富勒烯家族与碳簇最相关,其中一些可能是由于撞击激光破坏了实心碳相的形成。我们表明,检测到的富勒烯不是以这种方式形成的。我们建议富勒烯是尚未确定的特定碳相的内在组成部分。在使用相同的实验条件的同时,在默奇森和阿伦德大体样品中富勒烯的非探测表明,这些阶段在这些原始的软骨中不存在或较少。前一种情况将通过对尿素母体中碳质相的冲击处理来支持富勒伦的形成。但是,没有实验数据可以支持这种情况。这留下了富勒烯是星际遗产和星际过程的使者的可能性。

Buckminsterfullerene, C60 , is the largest molecule observed to date in interstellar and circumstellar environments. The mechanism of formation of this molecule is actively debated. Despite targeted searches in primitive carbonaceous chondrites, no unambiguous detection of C60 in a meteorite has been reported to date. Here we report the first firm detection of fullerenes, from C30 to at least C100 , in the Almahata Sitta (AhS) polymict ureilite meteorite. This detection was achieved using highly sensitive laser desorption laser ionization mass spectrometry. Fullerenes have been unambiguously detected in seven clasts of AhS ureilites. Molecular family analysis shows that fullerenes are from a different reservoir compared to the polycyclic aromatic hydrocarbons detected in the same samples. The fullerene family correlates best with carbon clusters, some of which may have been formed by the destruction of solid carbon phases by the impacting laser. We show that the detected fullerenes are not formed in this way. We suggest that fullerenes are an intrinsic component of a specific carbon phase that has yet to be identified. The nondetection of fullerenes in the Murchison and Allende bulk samples, while using the same experimental conditions, suggests that this phase is absent or less abundant in these primitive chondrites. The former case would support the formation of fullerenes by shock-wave processing of carbonaceous phases in the ureilite parent body. However, there are no experimental data to support this scenario. This leaves open the possibility that fullerenes are an interstellar heritage and a messenger of interstellar processes.

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