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Extracting biographical information from online documents is a popular research topic among the information extraction (IE) community. Various natural language processing (NLP) techniques such as text classification, text summarisation and relation extraction are commonly used to achieve this. Among these techniques, RE is the most common since it can be directly used to build biographical knowledge graphs. RE is usually framed as a supervised machine learning (ML) problem, where ML models are trained on annotated datasets. However, there are few annotated datasets for RE since the annotation process can be costly and time-consuming. To address this, we developed Biographical, the first semi-supervised dataset for RE. The dataset, which is aimed towards digital humanities (DH) and historical research, is automatically compiled by aligning sentences from Wikipedia articles with matching structured data from sources including Pantheon and Wikidata. By exploiting the structure of Wikipedia articles and robust named entity recognition (NER), we match information with relatively high precision in order to compile annotated relation pairs for ten different relations that are important in the DH domain. Furthermore, we demonstrate the effectiveness of the dataset by training a state-of-the-art neural model to classify relation pairs, and evaluate it on a manually annotated gold standard set. Biographical is primarily aimed at training neural models for RE within the domain of digital humanities and history, but as we discuss at the end of this paper, it can be useful for other purposes as well.