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In recent hyperspectral unmixing (HU) literature, the application of deep learning (DL) has become more prominent, especially with the autoencoder (AE) architecture. We propose a split architecture and use a pseudo-ground truth for abundances to guide the `unmixing network' (UN) optimization. Preceding the UN, an `approximation network' (AN) is proposed, which will improve the association between the centre pixel and its neighbourhood. Hence, it will accentuate spatial correlation in the abundances as its output is the input to the UN and the reference for the `mixing network' (MN). In the Guided Encoder-Decoder Architecture for Hyperspectral Unmixing with Spatial Smoothness (GAUSS), we proposed using one-hot encoded abundances as the pseudo-ground truth to guide the UN; computed using the k-means algorithm to exclude the use of prior HU methods. Furthermore, we release the single-layer constraint on MN by introducing the UN generated abundances in contrast to the standard AE for HU. Secondly, we experimented with two modifications on the pre-trained network using the GAUSS method. In GAUSS$_\textit{blind}$, we have concatenated the UN and the MN to back-propagate the reconstruction error gradients to the encoder. Then, in the GAUSS$_\textit{prime}$, abundance results of a signal processing (SP) method with reliable abundance results were used as the pseudo-ground truth with the GAUSS architecture. According to quantitative and graphical results for four experimental datasets, the three architectures either transcended or equated the performance of existing HU algorithms from both DL and SP domains.