论文标题

水合有机物:与海洋泥的质量物理静态和动态特性的功能关系

Hydrated Organic Matter: Functional Relationships with the Mass Physical Static and Dynamic Properties of Marine Mud

论文作者

Bennett, Richard H., Hulbert, Matthew H., Meredith, Roger W.

论文摘要

海洋泥浆沉积物的质量物理和动态特性是最多四个沉积物相之间相互作用的函数,如下所示:(1)粘土矿物质固体通常包括不同矿物学的淤泥和砂尺寸颗粒,(2)半固体水合有机物,(3)自由毛水和(4)何时自由气体。从历史上看,总水是通过烤箱干去除的,其中包括有机物水合的海水(OM);因此,在几个研究学科中,总水含量被认为是游离孔隙水。半固体水合的OM抵抗通过泥孔空间运输,与OM结合的水不是自由的孔隙水。在没有考虑和校正水合有机物的情况下计算海洋泥浆质量物质特性,可能会在泥浆空间中孔隙空间的游离水含量量以及孔隙率和空隙比的定量差异引起明显的误差。模拟揭示了由于水合OM的存在而导致的绝对相对差异,即使%TOC值低于3%,也可以达到有意义的值。相关性是通过比较由于水合OM相引起的差异与流体饱和阶段的差异在100%和90%时的差异来确定的。有望了解水合OM的存在和特征将在几项科学以及陆地和海洋泥浆沉积的岩土工程中吸引重要的未来研究。

The mass physical and dynamic properties of marine mud deposits are a function of the interaction among a maximum of four sediment Phases as follows: (1) clay mineral solids that often include silt and sand size particles of different mineralogy, (2) semisolid hydrated organic matter, (3) free pore water, and (4) free gas when present. Historically, the total water was removed by oven drying which includes the seawater of hydration of the organic matter (OM); thus, the total water content was considered free pore water in several research disciplines. The semisolid hydrated OM resists transport through the mud pore space and the water that is bound to the OM is not free pore water. Calculations of marine mud mass-physical properties without consideration and correction for the presence of hydrated organic matter can introduce significant error in the amount of free water content of the pore space in the mud and the quantitative differences in both porosity and void ratio. Simulations reveal absolute relative differences due to the presence of hydrated OM that can reach meaningful values even when the %TOC values are below ~3%. Relevance is determined by comparing the differences due to the hydrated OM Phase with the differences in the fluid saturation Phase at 100% and at 90%. Understanding the presence and characteristics of hydrated OM is expected to engage important future research in several sciences and in geotechnical engineering of terrestrial and marine mud deposits.

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