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We propose a braneworld scenario in a modified symmetric teleparallel gravitational theory, where the dynamics for the gravitational field is encoded in the nonmetricity tensor rather than in the curvature. Assuming a single real scalar field with a sine-Gordon self-interaction, the generalized quadratic nonmetricity invariant $\mathbb{Q}$ controls the brane width while keeping the shape of the energy density. By considering power corrections of the invariant $\mathbb{Q}$ in the gravitational Lagrangian, the sine-Gordon potential is modified exhibiting new barriers and false vacuum. As a result, the domain wall brane obtains an inner structure, and it undergoes a splitting process. In addition, we also propose a non-minimal coupling between a bulk fermion field and the nonmetricity invariant $\mathbb{Q}$. Such geometric coupling leads to a massless chiral fermion bound to the 3-brane and a stable tower of non-localized massive states.