论文标题

腔诱导的经典速率理论分叉

Cavity-induced bifurcation in classical rate theory

论文作者

Kansanen, Kalle S. U., Heikkilä, Tero T.

论文摘要

我们展示了将双态系统与共同腔场的耦合耦合如何影响该合奏的集体随机行为。特别是,该腔提供了系统之间的有效相互作用,并参数修改了亚稳态状态之间的过渡速率。我们预测,腔体在临界温度下诱导集体相变,这取决于系统数量。它显示为自发对称性破裂,在双叉系统的固定状态下。我们观察到过渡速率独立于相变的速度放慢速度,但是对于系统腔耦合的交替迹象的速率修改消失,对应于偶极子的无序集合。我们的结果在极化化学方面特别相关,在偏振化学中,已经提出了腔体影响化学反应。

We show how coupling an ensemble of bistable systems to a common cavity field affects the collective stochastic behavior of this ensemble. In particular, the cavity provides an effective interaction between the systems, and parametrically modifies the transition rates between the metastable states. We predict that the cavity induces a collective phase transition at a critical temperature which depends linearly on the number of systems. It shows up as a spontaneous symmetry breaking where the stationary states of the bistable system bifurcate. We observe that the transition rates slow down independently of the phase transition, but the rate modification vanishes for alternating signs of the system-cavity couplings, corresponding to a disordered ensemble of dipoles. Our results are of particular relevance in polaritonic chemistry where the presence of a cavity has been suggested to affect chemical reactions.

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