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Bisimulation metrics define a distance measure between states of a Markov decision process (MDP) based on a comparison of reward sequences. Due to this property they provide theoretical guarantees in value function approximation (VFA). In this work we first prove that bisimulation and $π$-bisimulation metrics can be defined via a more general class of Sinkhorn distances, which unifies various state similarity metrics used in recent work. Then we describe an approximate policy iteration (API) procedure that uses a bisimulation-based discretization of the state space for VFA and prove asymptotic performance bounds. Next, we bound the difference between $π$-bisimulation metrics in terms of the change in the policies themselves. Based on these results, we design an API($α$) procedure that employs conservative policy updates and enjoys better performance bounds than the naive API approach. We discuss how such API procedures map onto practical actor-critic methods that use bisimulation metrics for state representation learning. Lastly, we validate our theoretical results and investigate their practical implications via a controlled empirical analysis based on an implementation of bisimulation-based API for finite MDPs.