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In this paper, we report 591 high velocity star candidates (HiVelSCs) selected from over 10 million spectra of the data release seven (DR7) of the Large Sky Area Multi-object Fiber Spectroscopic Telescope and the second Gaia data release, with three-dimensional velocities in the Galactic rest-frame larger than 445 km/s. We show that at least 43 HiVelSCs are unbound to the Galaxy with escape probabilities larger than 50%, and this number decreases to eight if the possible parallax zero-point error is corrected. Most of these HiVelSCs are metal-poor and slightly alpha-enhanced inner halo stars. Only 14% of them have [Fe/H] > -1, which may be the metal-rich "in situ" stars in halo formed in the initial collapse of the Milky Way or metal-rich stars formed in the disk or bulge but kinematically heated. The low ratio of 14% implies that the bulk of stellar halo was formed from the accretion and tidal disruption of satellite galaxies. In addition, HiVelSCs on the retrograde orbits have a slightly lower metallicities on average compared with these on the prograde orbits, meanwhile metal-poor HiVelSCs with [Fe/H] < -1 have an even faster mean retrograde velocity compared with metal-rich HiVelSCs. To investigate the origins of HiVelSCs, we perform orbit integrations and divide them into four types, i.e., hypervelocity stars, hyper-runaway stars, runaway stars and fast halo stars. A catalog for these 591 HiVelSCs, including radial velocities, atmospheric parameters, Gaia astrometric parameters, spatial positions, and velocities, etc., is available at http://paperdata.chinavo.org/LYB/lamostdr7_gaiadr2_hvs_591.csv.