论文标题
基于介孔二氧化硅的纳米棒作为催化纳米运动器:运动动力学研究
Nanorods based on mesoporous silica containing iron oxide nanoparticles as catalytic nanomotors: study of motion dynamics
论文作者
论文摘要
自构的颗粒,尤其是基于中孔二氧化硅的颗粒,由于其在环境和生物医学领域的潜在应用,由于其生物相容性,可调的表面化学和较大的孔隙率,因此引起了很大的兴趣。尽管球形颗粒已被广泛用于制造纳米和微动物,但对其他几何形状(例如纳米棒)的关注不多。在这里,我们报告了通过溅射的PT层,Fe2O3纳米颗粒在中孔内生长的Fe2O3纳米颗粒或两者的协同组合的催化分解,或者报告了通过溅射的PT层催化过氧化氢的催化分解。我们表明,运动可能发生在两个不同的亚群中,这些群体以两个不同的运动动力学为特征,即增强的扩散或方向推进,尤其是在使用两种催化剂时。这些结果开辟了使用MSNR作为底盘的可能性,用于为环境或生物医学领域制造自螺旋颗粒。
Self-propelled particles and, in particular, those based on mesoporous silica, have raised considerable interest due to their potential applications in the environmental and biomedical fields thanks to their biocompatibility, tunable surface chemistry and large porosity. Although spherical particles have been widely used to fabricate nano- and micromotors, not much attention has been paid to other geometries, such as nanorods. Here, we report the fabrication of self-propelled mesoporous silica nanorods (MSNRs) that move by the catalytic decomposition of hydrogen peroxide by a sputtered Pt layer, Fe2O3 nanoparticles grown within the mesopores, or the synergistic combination of both. We show that motion can occur in two distinct sub-populations characterized by two different motion dynamics, namely enhanced diffusion or directional propulsion, especially when both catalysts are used. These results open up the possibility of using MSNRs as chassis for the fabrication of self-propelled particles for the environmental or biomedical fields.