论文标题

倾向于工程固有的线宽和钙钛矿纳米板的线路。

Towards Engineering Intrinsic Linewidths and Line-Broadening in Perovskite Nanoplatelets

论文作者

Liu, Albert, Nagamine, Gabriel, Bonato, Luiz G., Almeida, Diogo B., Zagonel, Luiz F., Nogueira, Ana F., Padilha, Lazaro A., Cundiff, Steven T.

论文摘要

钙钛矿纳米片具有极为狭窄的吸收和发射线宽,这是许多光学应用的关键特征。但是,它们的潜在固有和外部线路开发机制知之甚少。在这里,我们采用多维相干光谱,以确定胶体钙钛矿纳米骨骼集合的均匀线路。我们不仅可以控制其内在的线宽,还通过调整血小板几何形状来控制各种拓宽机制。值得注意的是,我们发现单个多面层层减少纳米血小板的厚度会导致不均匀的线宽降低2倍,并降低3倍的固有均质线宽到Sub-Mev状态。此外,我们的测量结果表明,在室温下(但不一定是4层)纳米片的激子共振。

Perovskite nanoplatelets possess extremely narrow absorption and emission linewidths, which are crucial characteristics for many optical applications. However, their underlying intrinsic and extrinsic line-broadening mechanisms are poorly understood. Here, we apply multi-dimensional coherent spectroscopy to determine the homogeneous line-broadening of colloidal perovskite nanoplatelet ensembles. We demonstrate control of not only their intrinsic linewidths, but also control of various broadening mechanisms by tuning the platelet geometry. Remarkably, we find that decreasing nanoplatelet thickness by a single polyhedral layer results in a 2-fold reduction of the inhomogeneous linewidth and a 3-fold reduction of the intrinsic homogeneous linewidth to the sub-meV regime. In addition, our measurements suggest homogeneously broadened exciton resonances in 3-layer (but not necessarily 4-layer) nanoplatelets at room-temperature.

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