论文标题

灯笼超水的结构不稳定性的边缘高温超导性

High-temperature superconductivity on the verge of a structural instability in lanthanum superhydride

论文作者

Sun, Dan, Minkov, Vasily S., Mozaffari, Shirin, Chariton, Stella, Prakapenka, Vitali B., Eremets, Mikhail I., Balicas, Luis, Balakirev, Fedor F.

论文摘要

预计1960年代金属氢会预测高室温超导性的可能性。但是,氢的金属化和超导性尚未在实验室中明确证明,可能需要高达500万个大气的压力。基于稀土的“超级氢”(例如LAH10)也可以被认为是金属氢的紧密近似值,即使它们在适度较低的压力下形成。在超水中,H-H金属键和高超导过渡温度的优势是金属氢的标志。尽管如此,揭示控制其超导性的关键因素的实验研究很少。在这里,我们报告了在LAH10中观察到的超导顺序的压力和磁场响应。对于LAH10,我们发现超导性与结构不稳定性之间存在相关性,强烈影响负责超导性的晶格振动。

A possibility of high, room-temperature superconductivity was predicted for metallic hydrogen in the 1960s. However, metallization and superconductivity of hydrogen are yet to be unambiguously demonstrated in the laboratory and may require pressures as high as 5 million atmospheres. Rare earth based "superhydrides" such as LaH10 can be considered a close approximation of metallic hydrogen even though they form at moderately lower pressures. In superhydrides the predominance of H-H metallic bonds and high superconducting transition temperatures bear the hallmarks of metallic hydrogen. Still, experimental studies revealing the key factors controlling their superconductivity are scarce. Here, we report on the pressure and magnetic field response of the superconducting order observed in LaH10. For LaH10 we find a correlation between superconductivity and a structural instability, strongly affecting the lattice vibrations responsible for the superconductivity.

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