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We study the spontaneous scalarization of a standard conducting charged sphere embedded in Maxwell-scalar models in flat spacetime, wherein the scalar field $ϕ$ is nonminimally coupled to the Maxwell electrodynamics. This setup serves as a toy model for the spontaneous scalarization of charged (vacuum) black holes in Einstein-Maxwell-scalar (generalized scalar-tensor) models. In the Maxwell-scalar case, unlike the black hole cases, closed-form solutions exist for the scalarized configurations. We compute these configurations for three illustrations of nonminimal couplings: one that \textit{exactly} linearizes the scalar field equation, and the remaining two that produce nonlinear continuations of the first one. We show that the former model leads to a runaway behaviour in regions of the parameter space and neither the Coulomb nor the scalarized solutions are stable in the model; but the latter models can heal this behaviour producing stable scalarized solutions that are dynamically preferred over the Coulomb one. This parallels reports on black hole scalarization in the extended-scalar-Gauss-Bonnet models. Moreover, we analyse the impact of the choice of the boundary conditions on the scalarization phenomenon. Dirichlet and Neumann boundary conditions accommodate both (linearly) stable and unstable parameter space regions, for the scalar-free conducting sphere; but radiative boundary conditions always yield an unstable scalar-free solution and preference for scalarization. Finally, we perform numerical evolution of the full Maxwell-scalar system, following dynamically the scalarization process. They confirm the linear stability analysis and reveal that the scalarization phenomenon can occur in qualitatively distinct ways.