论文标题

高于550 K以上的热氢化物超导性

Hot Hydride Superconductivity above 550 K

论文作者

Grockowiak, A. D., Ahart, M., Helm, T., Coniglio, W. A., Kumar, R., Somayazulu, M., Meng, Y., Oliff, M., Williams, V., Ashcroft, N. W., Hemley, R. J., Tozer, S. W.

论文摘要

The search for room temperature superconductivity has accelerated dramatically in the last few years driven largely by theoretical predictions that first indicated alloying dense hydrogen with other elements could produce conventional phonon-mediated superconductivity at very high temperatures and at accessible pressures, and more recently, with the success of structure search methods that have identified specific candidates and pressure-temperature (P-T) conditions for synthesis.这些理论进步促使实验技术的改进以测试这些预测。结果,在压力下对简单二进制氢化物的实验研究产生了高临界超导过渡温度(TC),在LAH10中为260 K,接近室温的普遍接受阈值,在293 K的室温下,在180 GPA附近的压力下。我们成功地合成了来自La Metal和Ammonia Borane(NH3BH3)的金属LA基超水,并找到了最高发病的TC的多步型过渡。当经过随后的热偏移到较高的温度,促进了对我们认为是三元或高阶系统的化学反应时,过渡温度被驱动到更高的温度。尽管反应似乎没有完成,但在必须终止实验之前,开始温度从294 K推至556 K。结果为高于室温的热超导性提供了证据,这与最近在压力下对高阶氢化物的预测一致。

The search for room temperature superconductivity has accelerated dramatically in the last few years driven largely by theoretical predictions that first indicated alloying dense hydrogen with other elements could produce conventional phonon-mediated superconductivity at very high temperatures and at accessible pressures, and more recently, with the success of structure search methods that have identified specific candidates and pressure-temperature (P-T) conditions for synthesis. These theoretical advances have prompted improvements in experimental techniques to test these predictions. As a result, experimental studies of simple binary hydrides under pressure have yielded high critical superconducting transition temperatures (Tc), of 260 K in LaH10, close to the commonly accepted threshold for room temperature, 293 K, at pressures near 180 GPa. We successfully synthesized a metallic La-based superhydride from La metal and ammonia borane, NH3BH3, and find a multi-step transition with a Tc of 294 K for the highest onset. When subjected to subsequent thermal excursions to higher temperatures that promoted a chemical reaction to what we believe is a ternary or higher order system, the transition temperature was driven to higher temperatures. Although the reaction does not appear to be complete, the onset temperature was pushed from 294 K to 556 K before the experiments had to be terminated. The results provide evidence for hot superconductivity well above room temperature, in line with recent predictions for a higher order hydride under pressure.

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