论文标题
与多个衰减通道的模式耦合理论的缩放方程
Scaling equations for mode-coupling theories with multiple decay channels
论文作者
论文摘要
多个放松通道通常在液体的动力学中出现,其中与颗粒保存法相关的动量电流分为不同的贡献。例子是强烈的液体,朝向墙壁的横向和纵向方向的电流非常不同,或者是非球形颗粒的流体,具有独特的弛豫模式,可转化和旋转自由度。在这里,我们对模式耦合理论(MCT)与多个弛豫通道所描述的那样,对接近动力学停滞的缓慢结构弛豫进行渐近分析。与标准MCT相比,多个弛豫通道的存在显着改变了基础运动方程的结构,并导致渐近溶液中的其他非平凡项。我们表明该解决方案可以重新固定,因此证明了众所周知的MCT的$β$尺度方程,即使在存在多个弛豫通道的情况下,也是有效的。使用新型的示意图验证了渐近处理。我们证明,该示意图模型的数值解确实可以通过接近动力学停滞的衍生渐近缩放定律来描述。此外,在低频易感频谱中发现了存在两个不同衰减通道的清晰痕迹,这表明在限制或分子液体的模拟或实验中,可以原理检测到附加弛豫通道的清晰足迹。
Multiple relaxation channels often arise in the dynamics of liquids where the momentum current associated to the particle-conservation law splits into distinct contributions. Examples are strongly confined liquids for which the currents in lateral and longitudinal direction to the walls are very different, or fluids of nonspherical particles with distinct relaxation patterns for translational and rotational degrees of freedom. Here, we perform an asymptotic analysis of the slow structural relaxation close to kinetic arrest as described by mode-coupling theory (MCT) with several relaxation channels. Compared to standard MCT, the presence of multiple relaxation channels significantly changes the structure of the underlying equations of motion and leads to additional, non-trivial terms in the asymptotic solution. We show that the solution can be rescaled, and thus prove that the well-known $ β$-scaling equation of MCT remains valid even in the presence of multiple relaxation channels. The asymptotic treatment is validated using a novel schematic model. We demonstrate that the numerical solution of this schematic model can indeed be described by the derived asymptotic scaling laws close to kinetic arrest. Additionally, clear traces of the existence of two distinct decay channels are found in the low-frequency susceptibility spectrum, suggesting that clear footprints of the additional relaxation channels can in principle be detected in simulations or experiments of confined or molecular liquids.