论文标题

From magnetic order to quantum disorder: a $μ$SR study of the Zn-barlowite series of $S={\frac{1}{2}}$ kagomé antiferromagnets, Zn$_{x}$Cu$_{4-x}$(OH)$_{6}$FBr

From magnetic order to quantum disorder: a $μ$SR study of the Zn-barlowite series of $S={\frac{1}{2}}$ kagomé antiferromagnets, Zn$_{x}$Cu$_{4-x}$(OH)$_{6}$FBr

论文作者

Tustain, K., Ward-O'Brien, B., Bert, F., Han, T. -H., Luetkens, H., Lancaster, T., Huddart, B. M., Baker, P. J., Clark, L.

论文摘要

我们报告了$ s = {\ frac {\ frac {1} {2}} $kagoméantiferRomagnets,Zn $ _x $ _x $ _x $ _ cu $ _ {4-x} $ _ {6} $ _ {6} $ fbr,flbr,flbr,$ x = 0.0.00 $ x = 0.00。通过将MUON自旋松弛和旋转测量与最先进的密度功能理论MUON位点计算相结合,我们观察到$μ$ - F和$μ$的形成 - Zn-Barlowite中的OH Complextes。从这些停止位点,植入的μ子旋转在增加Zn替代浓度后,将远程磁性抑制抑制为可能的量子旋转液态。在父级化合物($ x = 0 $)中,低于$ t _ {\ mathsf {n}} = 15 $ k以下的静态长距离磁性顺序以自发振荡的形式表现在时间相关的muon不对称信号中,这与先前确定的磁性磁性磁性磁性结构相关的二极化信号一致。 Meanwhile, in the $x=1.0$ end-member of the series---in which antiferromagnetic kagomé layers of Cu$^{2+}$ $S={\frac{1}{2}}$ moments are decoupled by diamagnetic Zn$^{2+}$ ions---we observe that dynamic magnetic moment fluctuations persist down to at least 50 MK,指示量子无序的基态。我们证明,从静态到动态磁接地状态的这种交叉发生在Zn-Barlowite的组成中,$ x> 0.5 $,这与广泛研究的Zn-Paratacamite系列的动态行为相似,该Zn- paratacamite系列包含量子旋转的液体液体候选者Herbertsmithite。

We report a comprehensive muon spectroscopy study of the Zn-barlowite series of $S={\frac{1}{2}}$ kagomé antiferromagnets, Zn$_x$Cu$_{4-x}$(OH)$_{6}$FBr, for $x=0.00$ to $0.99(1)$. By combining muon spin relaxation and rotation measurements with state-of-the-art density-functional theory muon-site calculations, we observe the formation of both $μ$--F and $μ$--OH complexes in Zn-barlowite. From these stopping sites, implanted muon spins reveal the suppression of long-range magnetic order into a possible quantum spin liquid state upon increasing concentration of Zn-substitution. In the parent compound ($x=0$), static long-range magnetic order below $T_{\mathsf{N}}=15$ K manifests itself in the form of spontaneous oscillations in the time-dependent muon asymmetry signal consistent with the dipolar fields expected from the calculated muon stopping sites and the previously determined magnetic structure of barlowite. Meanwhile, in the $x=1.0$ end-member of the series---in which antiferromagnetic kagomé layers of Cu$^{2+}$ $S={\frac{1}{2}}$ moments are decoupled by diamagnetic Zn$^{2+}$ ions---we observe that dynamic magnetic moment fluctuations persist down to at least 50 mK, indicative of a quantum disordered ground state. We demonstrate that this crossover from a static to dynamic magnetic ground state occurs for compositions of Zn-barlowite with $x>0.5$, which bears resemblance to dynamical behaviour of the widely studied Zn-paratacamite series that contains the quantum spin liquid candidate herbertsmithite.

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