论文标题
对“卤化物钙壶中的低频晶格声子的评论回应，解释了对电子孔重组的高缺陷耐受性”
Response to Comment on "Low-frequency lattice phonons in halide perovskites explain high defect tolerance toward electron-hole recombination"
论文作者
论文摘要
最近，我们提出，混合钙钛矿中的缺陷耐受性是由于其特征性的低频晶格声子模式，从而降低了非绝热耦合并削弱了自由载体和缺陷状态之间的重叠[SCI。 ADV。 6 7，EAAW7453（2020）]。金和沃尔什不同意这种解释，并认为我们使用的方法中存在缺陷。在此，我们解决了他们的担忧，并表明由于对非绝热过渡的误解，他们的结论无效。
Recently we proposed that defect tolerance in the hybrid perovskites is due to their characteristic low-frequency lattice phonon modes that decrease the non-adiabatic coupling and weaken the overlap between the free carrier and defect states [Sci. Adv. 6 7, eaaw7453 (2020)]. Kim and Walsh disagree with the interpretation and argue that there are flaws in our employed methodology. Herein we address their concerns and show that their conclusions are not valid due to misunderstandings of nonadiabatic transition.
