论文标题
通过多体片段化动力学解开基准分子H2O2的分子本质
Disentangling the molecular nature of the benchmark molecule H2O2 through many-body fragmentation dynamics
论文作者
论文摘要
从相当长的时期开始，分裂中的普遍性一直是科学利益的框架，以消除原子和分子的结构和动力学。然而，朝这个方向的研究仍然难以捉摸无法探索多原子分子的细节，因为它们在结构和电子电子相关性方面的复杂性。因此，这里报道了多原子过氧化氢（H2O2）在大气物理和化学中起决定性作用的多体体碎片化动力学，并且实际上在星际培养基中发现了这一点。 H2O23+的三体解离，构成了本文的主要主题，特别是关于H2O2中发生的顺序和非顺序片段化途径以及顺式和反式异构体。除这些细节外，该文章还包括H2O24+/5+的四体解离动力学，这些动力学已用于研究H2O2中的结构性手续性。
Universality in fragmentation has been the framework of scientific interest from a considerable period to disentangle the structure and dynamics of atoms and molecules. Studies in this direction however are still elusive to explore the details about polyatomic molecules because of their complexity in structure and electron-electron correlations. Hence many-body fragmentation dynamics of polyatomic hydrogen peroxide (H2O2) that plays a decisive role in atmospheric physics and chemistry and indeed which has been discovered recently in interstellar medium, is reported here. The three-body dissociation of H2O23+ which forms the main subject of this article discusses here particularly about the sequential and non-sequential fragmentation pathways and cis- and trans-isomerism that takes place in H2O2. In addition to these details, the article also includes four-body dissociation dynamics of H2O24+/5+ that has been employed to investigate the structural-chirality in H2O2.
