论文标题
对离子解决方案的连续模型的简要综述:泊松玻璃到托管及相关理论
A Brief Review of Continuous Models for Ionic Solutions: the Poisson-Boltzmann and Related Theories
论文作者
论文摘要
Poisson-Boltzmann(PB)理论是不断描述带电系统的最重要的理论模型之一。但是,它遭受了忽视离子相关性的困扰,这阻碍了其适用于更通用的电荷系统以外的其他稀释系统。因此,开发了一些修改后的PB理论版本,以有效地包括离子相关性。在本文中对其优势和局限性的诊断,对其针对离子溶液的应用,原始的PB理论及其方差,包括现场理论方法,相关增强的PB模型,Outhwaite-Bhuiyan修改的PB理论和平均野外理论。
The Poisson-Boltzmann (PB) theory is one of the most important theoretical models describing charged systems continuously. However, it suffers from neglecting ion correlations, which hinders its applicability to more general charged systems other than extremely dilute ones. Therefore, some modified versions of the PB theory are developed to effectively include ion correlations. Focused on their applications to ionic solutions, the original PB theory and its variances, including the field-theoretic approach, the correlation-enhanced PB model, the Outhwaite-Bhuiyan modified PB theory and the mean field theories, are briefly reviewed in this paper with the diagnosis of their advantages and limitations.